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AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
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STUDIA GEOLOGIA - Ediţia nr.3 din 2003 | |||||||
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ISOMORPHIC SUBSTITUTIONS IN HIGH AND LOW VESUVIANITE STRUCTURE. Autori: ELENA YU. BOROVIKOVA. |
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Rezumat: Vesuvianite is an ortho-disilicate with complicated chemistry. Its general formula can be written as X19Y13Z18O68T0-5W10, where X is Ca and other large cations occupying 8-coordinate sites, Y are cations occupying 6 and 5-coordinate sites, as Al, Mg, Fe, Ti etc., Z are Si occupying 4-coordinate sites, T is B in 3 and 4-coordinate sites, and W are monovalent and divalent anions: OH-, F or O. Depending on atoms ordering in the structure, vesuvianite crystallizes in P4/nnc (high) or P4/n (low) space group. Low vesuvianite occurs in metamorphic rocks formed at low temperatures [< 300ºC, compared to those containing high vesuvianite (400 - 800ºC)]. A collection of more than 50 vesuvianite samples was investigated by a number of analytical methods such as electron microprobe analysis, IR-spectroscopy, Mössbauer spectroscopy and others. Vesuvianite samples were separated accordingly to their space groups, identified by IR-spectra. ... | |||||||
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