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    STUDIA CHEMIA - Ediţia nr.1 din 2024  
         
  Articol:   GC-MS COMPARATIVE CHEMICAL COMPOSITION OF ESSENTIAL OILS AND VOLATILE COMPOUNDS OF ERYNGIUM PLANUM L. USING CLASSICAL HYDRODISTILLATION, ULTRASOUND-ASSISTED HYDRODISTILLATION AND HEADSPACE SOLID-PHASE MICROEXTRACTION. ANTIMICROBIAL ACTIVITY.

Autori:  ADRIANA-MARIA ANDREICA, ANA BALEA, MARIA POJAR-FENEȘAN, RAHELA CARPA.
 
       
         
  Rezumat:  
DOI: 10.24193/subbchem.2024.1.09

Published Online: 2024-03-30
Published Print: 2024-03-30
pp. 147-161

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This study presents the extraction of essential oils and volatiles of Eryngium planum (E. planum) by classical hydrodistillation (HD), ultrasound-assisted hydrodistillation (UAHD) and headspace solid-phase microextraction (HS-SPME). The GC-MS analysis showed that the essential oil of E. planum obtained by UAHD contains the following majority compounds: β-copaene (11.97%), cis-chrysanthenyl acetate (10.14%), (E)-β-farnesene (6.79%), γ-gurjunene (6.53%), caryophyllene (5.73%), germacrene B (3.93%), (+)-cis-verbenol,2-methylpropionate (2.87%), β-selinene (2.73%). The GC-MS analysis showed that E. planum volatiles extracted by HS-SPME contains, as majority compounds, the following elements: cis-chrysanthenyl acetate (30.39%), (E)-β-farnesene (11.71%), γ-maaliene (7.69%), β-elemene (7.26%), caryophyllene (6.5%), β-selinene (4.72%), δ-cadinene (4.72%), β-copaene (4.61%), α-pinene (4.51%), γ-muurolene (2.98%). By using the UAHD method, the yield of E. planum oil was increased by 27.27% compared with the classical HD method. The essential oil of E. planum showed an excellent antimicrobial activity against Escherichia coli and Staphylococcus aureus.

Keywords: Eryngium planum, essential oils, ultrasound-assisted hydrodistillation (UAHD), headspace solid-phase microextraction (HS-SPME), antimicrobial activity
 
         
     
         
         
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