AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
The STUDIA UNIVERSITATIS BABEŞ-BOLYAI issue article summary
The summary of the selected article appears at the bottom of the page. In order to get back to the contents of the issue this article belongs to you have to access the link from the title. In order to see all the articles of the archive which have as author/co-author one of the authors mentioned below, you have to access the link from the author's name.
Authors: R. TETEAN.
Published Online: 2017-01-05
Published Print: 2017-01-31
VIEW PDF: MAGNETOCALORIC AND MAGNETIC PROPERTIES OF NANOCRYSTALLINE La0.75Pb0.25MnO3
Nanocrystalline La0.75Pb0.25MnO3 powders were synthesized by grinding the constituent oxides in air at room temperature, using a high-energy planetary mill. The reaction process, evaluated by analyzing the evolution of the crystalline structure in the XRD patterns, is completed after about 12 h. The magnetic measurements indicate that the manganite nanoparticles with sizes smaller than 15 nm obtained by reacting milling have significant defects at the surface, leading to a serious decrease of the magnetic moments in comparison to the bulk material. A significant magnetocaloric effect was found at temperatures ranging from below to above room temperature, with the maximum entropy change located at temperatures near the magnetic transition one. The high RCP(S) values together with the broadened magnetic entropy curve suggest the possibility to use these materials for magnetic refrigeration devices.
Keywords: nanoparticles; LPMO; high energy ball milling; magnetocaloric effect
