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    STUDIA CHEMIA - Issue no. 4(II) / 2009  
         
  Article:   SYNTHESIS OF ESTER DERIVATIVES OF CALIX[N]ARENE.

Authors:  ALINA SAPONAR, ELISABETH-JEANNE POPOVICI, RODICA GRECU , IOAN SILAGHI-DUMITRESCU, NICOLAE POPOVICI.
 
       
         
  Abstract:  The synthesis of p-tert-butyl calix[n]arene derivatives with two and four, as well as, four and six (ethoxycarbonyl)methoxy groups at the lower rim is reported. The selective alkylation of the parent calix[n]arenes is performed in organic solvents, with ethyl bromoacetate in the presence of potassium carbonate or sodium hydride as a base. UV-Vis, FTIR, 1H-NMR investigations confirmed the formation of the ester derivatives of calix[n]arene with variable number of ester groups at the narrow rim.

Keywords: Calix[n]arene, selective O-alkylation, ethyl bromoacetate
 
         
     
         
         
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