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STUDIA CHEMIA - Issue no. 3 / 2024 | |||||||
Article: |
CATALYTIC AND SOLVENT HYDROTHERMAL LIQUEFACTION OF MICROALGAE: A STRATEGY FOR RECOVERING FINE CHEMICALS. Authors: SATHISH RAAM RAVICHANDRAN, CHITRA DEVI VENKATACHALAM, MOTHIL SENGOTTIAN. |
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Abstract: DOI: 10.24193/subbchem.2024.3.07 Published Online: 2024-09-30 Published Print: 2024-09-30 pp. 109-129 VIEW PDF FULL PDF The study investigates the influence of various catalysts (Ni/TiO2, Co/TiO2, and Zeolite) on the hydrothermal liquefaction of microalgae and explores the effect of co-solvents (acetone, methanol, and toluene) on biocrude yield from different microalgae three species namely Nannochloropsis oculata, Chlorella vulgaris, and Spirulina maxima. Catalyst characterization using FE-SEM, XRD, and BET analysis revealed distinct properties. Under Co-TiO2, Nannochloropsis oculata and Chlorella vulgaris yield 56.21% and 57.6% biocrude at 5% loading; Spirulina maxima yields 45.3% at 2.5% loading. With Ni-TiO2, Nannochloropsis oculata yields 52.4% at 2.5% loading; Chlorella vulgaris yields 44.7% at 5%; Spirulina maxima yields 44% at 2.5% loading. Zeolite yields: Spirulina maxima and Chlorella vulgaris yield 53.8% and 52.1% at 2.5%; Nannochloropsis oculata yields 48.3% at 7.5% loading. Co-solvent addition significantly boosts biocrude yield; methanol and toluene yield 53.7% and 49.2% for Chlorella vulgaris and Spirulina maxima, respectively, while acetone yields 57.6% for Nannochloropsis oculata. Different solvents extract diverse functional groups such as alkanes, halides, aromatics, and aldehydes which has wide industrial applications. Keywords: Biocrude, Catalysts, Co-Solvents, Hydrothermal Liquefaction, Microalgae |
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