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    STUDIA CHEMIA - Issue no. 2 / 2006  
         
  Article:   SYNTHESIS, SPECTRAL AND THERMAL STUDIES OF {[2-[(2,6-DICHLOROPHENYL)AMINO]PHENYL} ACETATE OF RUTHENIUM (III) AND RHODIUM (III).

Authors:  L. GHIZDAVU. 		 
       
         
  Abstract:  The reactions of RuCl3 and RhCl3 with deprotonated diclofenac (L) were studied in aqueous solution. Coordination compounds of the formulae [Ru(L)3 (H2O)3]3H2O and [Rh(L)3.(H2O)3].2H2O were isolated as solid products and characterized by elemental analyses and spectroscopic (IR, UV-VIS) and thermal studies. In all studied compounds, {2-[(2,6-dichlorophenyl)amino]-phenyl}acetate acts as monodentate ligand with coordinate involving the carboxylate oxygen atom.  
         
     
         
         
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