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    STUDIA CHEMIA - Issue no. 2 / 2003  
         
  Article:   FIRST EXAMPLE OF 1-AZA-3,7-DIOXABICYCLO[3.3.0]OCTANE-5-YL-METHOXY SYSTEM AS DIRECTED ORTHO-METALLATION GROUP.

Authors:  CAMELIA BERGHIAN, CARMEN MAIEREANU, NELLY PLÉ, ALAIN TURCK, ERIC CONDAMINE, MIRCEA DARABANTU.
 
       
         
  Abstract:  The first synthetic and stereochemical approach (supported by NMR data) is described for two title compounds by complete regioselective metallation of some -deficient systems of type pyrazine bearing a 1-aza-3,7-dioxabicyclo[3.3.0]octane-5-yl-methoxy fragment as directed ortho-metallating group.  
         
     
         
         
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