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    STUDIA CHEMIA - Issue no. 1-2 / 1998  
         
  Article:   THE SYNTHESIS AND THE STUDY OF THE COORDINATION POLYMERS OBTAINED BY THE INTERACTION BETWEEN PD(II) ACETYLACETONATE WITH DIPHENYLPHOSPHINIC, DIPHENYLTHIOPHOSPHINIC AND DIPHENYLDITHIOPHOSPHINIC ACIDS AS LIGANDS.

Authors:  IOAN ROŞCA, MIHAELA VIZITIU, DAN SUTIMAN, ADRIAN CĂILEAN, DOINA SIBIESCU, IULIAN RUSU.
 
       
         
  Abstract:  The synthesis and the study of some coordination polymers derived from the interaction of acetylacetonate of Rh(II) with diphenylphosphinic acid, dipheylthiophosphinic acid and diphenyldithiophosphinic acid are presented. The methods applied for the study are: chemical analysis, IR-absorption spectra, ESR, Spectroscopy, X-ray diffraction, the registration of some curves on a derivatograph and the determination of the kinetics parameters of the thermal decomposition reactions. Based on experimental data and on literature indications, the structural formulas of these compounds are assigned.  
         
     
         
         
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