AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
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STUDIA CHEMIA - Issue no. 1-2 / 1998 | |||||||
Article: |
THE SYNTHESIS AND THE STUDY OF THE COORDINATION POLYMERS OBTAINED BY THE INTERACTION BETWEEN PD(II) ACETYLACETONATE WITH DIPHENYLPHOSPHINIC, DIPHENYLTHIOPHOSPHINIC AND DIPHENYLDITHIOPHOSPHINIC ACIDS AS LIGANDS. Authors: IOAN ROŞCA, MIHAELA VIZITIU, DAN SUTIMAN, ADRIAN CĂILEAN, DOINA SIBIESCU, IULIAN RUSU. |
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Abstract: The synthesis and the study of some coordination polymers derived from the interaction of acetylacetonate of Rh(II) with diphenylphosphinic acid, dipheylthiophosphinic acid and diphenyldithiophosphinic acid are presented. The methods applied for the study are: chemical analysis, IR-absorption spectra, ESR, Spectroscopy, X-ray diffraction, the registration of some curves on a derivatograph and the determination of the kinetics parameters of the thermal decomposition reactions. Based on experimental data and on literature indications, the structural formulas of these compounds are assigned. | |||||||