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    STUDIA CHEMIA - Issue no. 1 / 2003  
         
  Article:   TEMPERATURE DEPENDENCE OF THE DIOXIMES HYDROLYSIS REACTION RATE.

Authors:  G. SZABÓ, JANOS ZSAKO, CS. BOLLA.
 
       
         
  Abstract:  Hydrolysis reaction of 1,2,3-cyclohexanetrione-1,3-dioxime and 1,2,3-cyclohexanetrione-2-imine-1,3-dioxime was studied in presence of different concentrations of perchloric acid and at different temperatures. The hydrolysis reaction was studied polarographically. Time course of diffusion current intensity was followed. Apparent rate constants were determined at different temperatures and activation parameters were calculated.  
         
     
         
         
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