AMBIENTUM BIOETHICA BIOLOGIA CHEMIA DIGITALIA DRAMATICA EDUCATIO ARTIS GYMNAST. ENGINEERING EPHEMERIDES EUROPAEA GEOGRAPHIA GEOLOGIA HISTORIA HISTORIA ARTIUM INFORMATICA IURISPRUDENTIA MATHEMATICA MUSICA NEGOTIA OECONOMICA PHILOLOGIA PHILOSOPHIA PHYSICA POLITICA PSYCHOLOGIA-PAEDAGOGIA SOCIOLOGIA THEOLOGIA CATHOLICA THEOLOGIA CATHOLICA LATIN THEOLOGIA GR.-CATH. VARAD THEOLOGIA ORTHODOXA THEOLOGIA REF. TRANSYLVAN
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STUDIA CHEMIA - Ediţia nr.3 din 2009 | |||||||
Articol: |
EQUILIBRIUM STUDY ON ADSORPTION PROCESSES OF 4-NITROPHENOL AND 2, 6-DINITROPHENOL ONTO GRANULAR ACTIVATED CARBON. Autori: MIHAELA-CLAUDIA TERTIŞ, FLORINA IONESCU, MARIA JITARU. |
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Rezumat: Adsorption of 4-nitrophenol and 2, 6-dinitrophenol onto granular activated carbon has been studied. Adsorption experiments were carried out in a batch system and were followed by UV-Visible spectroscopy over a period of 120 min. Adsorption isotherms were derived at 25oC and the isotherm data were treated according to Langmuir, Freundlich and Tempkin isotherm equations. The fitting of experimental data was tested and the parameters of these equations were determined. Based on the correlation coefficients both Langmuir and Freundlich models are suitable for the study (the squares of correlation coefficients are all > 0.97). Based on the values of normalized percent deviation P, the Freundlich model is suitable for 4-NP and the Langmuir model is suitable 2,6-DNP adsorption onto granular activated carbon type NORIT GAC 1240W (value of P less than 5). The calculated adsorption capacity values (qmax) are: 277.77 mg g-1 for 4-NP, respective 41.15 mg g-1 for 2, 6-DNP.
Keywords: adsorption, nitrophenols, isotherm, activated carbon |
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