Rezumat articol ediţie STUDIA UNIVERSITATIS BABEŞ-BOLYAI

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A bentonite sample from Oraşul Nou deposit, (Transilvania, Romania), was used to remove heavy metal ions (Zn²⁺, Pb²⁺, Cd²⁺) from model monocomponent wastewaters. A representative sample of bentonite (ON) was characterised using, wet chemical analyses, XRD, BET and FTIR. The bentonite deposit from Oraşul Nou formed by alteration of rhyolites and perlites. Mineralogically, they contain clay minerals (montmorillonite, and subordinately kaolinite, illite), cristobalite, carbonates, zeolites (clinoptilolite), iron oxi-hydroxides and relics of primary minerals such as quartz and feldspar.The bentonite sample was used as powder, (d < 0.2 mm), without any chemical treatment. We studied the influence of the working regime, static and dynamic, concentration, and solid : liquid ratio over the process efficiency. We used monocomponent synthetic wastewaters containing zinc, lead and cadmium ions. The bentonite sample proved to be efficient for the removal of the considered heavy metal ions, removal efficiencies up to 100% (lead and zinc removal) were reached. First-order, pseudo- second-order and Elovich models were used to study the adsorption kinetic of zinc ions on the bentonite sample.

 Keywords: bentonite, montmorillonite, zinc, lead, cadmium, removal